I suffer from painful Jaws, its because of my spine + i grind my teeth at night, meant to wear a gum shield and do exercises, but never bothered.
It is a condition and a very painful 1. ( my bottom jaw is mis-aligned.) I cant find the sheet i was given by the dental hospital, but found this, its almost exactly the same, more so with the tongue at the roof of the mouth, (and that does hurt.) If it dont settle Duffield see dentist and see if your jaws are out of true. (Teeth can be a problem for sore jaws.
Here is the Link.
http://www.ehow.com/how_2352238_cure-tmj-jaw-exercises.html
Just remembered an exercise i was given,and thats to Mime the Vowels,
A,E,I,O,U. in an exaggerated manner, this helps strengthen the jaws as well as facial muscles, less wrinkles as well.